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Which of the following is also known as wood spirit?

(a) Ethanol (b) Propanol

(c) Methanol (d) Butanol

Ans C

The action of zymase is inhibited during fermentation if the percentage of alcohol formed exceeds

(a) 5% (b) 7%

(c) 10% (d) 14%

Ans d

Vinylic alcohol contains

(a) -OH group attached to an sp3-hybridised carbon atom

(b) -OH group attached to sp3-hybridised carbon atom

(c) -OH group bonded to a carbon-carbon double bond

(d) -OH group attached to sp3-hybridised carbon atom

Ans C

In ethers, the two bond pairs and two lone pairs of electrons on oxygen are arranged in a

(a) planar arrangement

(b) tetrahedral arrangement

(c) trigonal bipyramidal arrangement

(d) linear arrangement

Ans B

The reagent(s) used for the reduction of aldehydes and ketone into alcohols is/are

(a) finely divided metals such as Pt/Pd/Ni

(b) sodium borohydride

(c) lithium aluminium hydride

(d) All of the above

Ans d

Which of the following reagent is used to reduce carboxylic acids to primary alcohols?

(a) Pd (b) R-OH (c) LiAlH4 (d) Ni

Ans C

The reaction of Grignard reagent with carbonyl compound is a nucleophilic addition reaction. This reaction on hydrolysis produces

(a) ester (b) alcohol

(c) carboxylic acid (d) ether

Ans b

Alcohols and phenols react with active metals to yield

(a) alkoxides/phenoxides (b) hydrogen gas

(c) nitrogen (d) Both (a) and (b)

Ans d

Phenols show the cleavage of C— O bond with

(a) Na (b) K

(c) Zn (d) Ca

Ans C

Phenol on reaction with conc. HNO3 produces

(a) o-nitrophenol (b) p-nitrophenol

(c) 2, 4, 6-trinitrophenol (d) m-nitrophenol

Ans c

Williamson’s synthesis involves which of the following type of mechanism when attack of an alkoxide ion on primary alkyl halide takes place?

(a) SN1 (b) SN2

(c) E1 (d) E2

Ans b

Among the following sets of reactants which one produces anisole?

(a) CH3CHO, RMgX

(b) C6H5OH, NaOH, CH3I

(c) C6H5OH, neutral FeCl3

(d) C6H5– CH3, CH3COCl , AlCl3

Ans b

Select the correct increasing order of boiling point.

(a) n-pentane, ethoxyethane, butan-1-ol

(b) ethoxyethane, n-pentane, butan-1-ol

(c) butan-1-ol, n-pentane, ethoxyethane

(d) ethoxyethane, butan-1-ol, n-pentane

Ans a

The order of reactivity of hydrogen halides with ether is as follows :

(a) HBr > HI > HCl (b) HCl > HBr > HI

(c) HI > HBr > HCl (d) HCl > HI > HBr

Ans c

Ethers are treated with an aqueous solution of I in order to remove peroxides from it. Identify the ‘I’ from the following options.

(a) KI (b) Br2

(c) KCNS (d) Na2S2O3

Ans a

Which of the following hydrocarbon is used for the world wide production of phenol?

(a) Iso-butylbenzene (b) Iso-propylbenzene

(c) Iso-pentylbenzene (d) None of these

Ans b

Arrange the following compounds in the decreasing order of acidity.

(a) H2O > HC≡CH>ROH

(b) H2O >ROH > HC≡CH

(c) HC≡CH>ROH > H2O

(d) HC≡CH> H2O >ROH

Ans b

Which one is the most acidic compound?

(a) (b)

(c) (d)

Ans d

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